水热碳化技术处理畜禽粪便的研究进展
作者:
作者单位:

作者简介:

通讯作者:

中图分类号:

基金项目:

国家重点研发计划项目(2019YFD0408700);国家重点研发计划项目(2016YFD0501402);中央高校基本科研业务费项目(FRF-IC-19-001)


Research progress of treatment of livestock manure by hydrothermal carbonization technology
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    水热碳化是一种实现废弃生物质高值化再利用的热化学转化技术,特别是针对含水率高的畜禽粪便处理,与其他碳化技术相比具有明显的优势,不仅能解决畜禽粪便随意堆积造成的环境污染问题,还能快速杀死致病微生物、获得高值生物炭产品,为实现畜禽养殖粪污减量化排放、资源化利用,推动乡村振兴、建设美丽乡村具有重要意义。文章基于畜禽粪便主要组分和水热碳化机理,重点介绍了温度、液固比、反应停留时间、添加剂等因素对水热炭产率及理化性质的影响,并讨论了水热炭作为生物燃料、吸附剂、土壤改良剂和功能材料前驱体的应用前景,为通过调整水热碳化过程参数以提高产物应用潜能提供参考。通过梳理,总结目前研究存在的问题,为未来研究工作指明方向,以期推动水热碳化技术在畜禽粪便处理和资源化利用的应用。

    Abstract:

    A large number of animal manures has been produced in China in recent years, due to the ever-increasing demand for livestock and poultry breeding. Improper disposal can pose potential environmental and health risks. Alternatively, hydrothermal carbonization has been one of the thermochemical technologies to convert the waste biomass into high value-added products without drying raw materials. Therefore, it is a highly promising potential to convert the animal manures into high value-added carbon-rich materials using hydrothermal carbonization, in order to prevent environmental pollution and pathogenic microbe spread from the random accumulation. This review aims to clarify the effects of temperature, liquid-solid ratio, reaction residence time, and additives on the yield and physicochemical properties of hydrochars, according to the main components of animal manures under hydrothermal carbonization. Some mechanisms were evaluated to determine the specific reaction pathways, including hydrolysis, dehydration, decarboxylation, aromatization, Mailard reaction, and polymerization. An interaction was also identified between various factors and reaction kinetics. Among them, the reaction temperature was the most critical factor affecting the reaction pathways and characteristics of products. A mathematical model was then established to describe the hydrothermal carbonization, further evaluating the application effect on laboratory and industrial scale. There was an increase in the temperature and residence time during hydrothermal carbonization, leading to the hydrochar with a higher carbon content and calorific value, but the yield decreased significantly. Furthermore, the volatile content of hydrochar decreased significantly after hydrothermal carbonization, which was related to the reduction of hydroxyl, and carboxyl functional groups. The heavy metals and phosphorus were often fixed in the hydrochars in more stable forms, whereas, nitrogen and potassium were transferred to the liquid products. Medium temperature (180-220 ℃) for a short time (0.5-2 h) was conducive to maintaining the nutrient elements in the hydrochar for the better capacity of soil water holding. Moreover, the hydrochar also varied in the surface functional groups and pore structure, thereby serving as the potential biofuel, adsorbent, soil amendment, and precursor of functional materials. More importantly, the addition of CaO was greatly contributed to the pH and yield of hydrochar in the process of hydrothermal carbonization, together with the improved pore structure and the number of surface functional groups. As such, the acid increased the calorific value, specific surface area, fixed carbon content, and H/C, O/C atomic ratio of hydrochar. Co-hydrothermal carbonization had avoided the weakness of hydrochar produced by a single feedstock with high ash and heavy metals content, which were possibly limited factors for the potential applications in energy materials and soil amendment. Consequently, the porous carbon materials with high specific surface area, excellent pore structure, and adjustable surface chemical properties can be widely expected to prepare in the activation and modification process with the livestock manure hydrochars as a precursor. Microwave-assisted hydrothermal carbonization of animal manures can also realize rapid heating to shorten the reaction time for the higher product yield. A further study needs to be focused on the economic feasibility and large-scale application. This finding can also provide a strong reference to promote the application potential of hydrothermal carbonization in the treatment of animal manures.

    参考文献
    相似文献
    引证文献
引用本文

李子富,于露,郑 蕾,郭佳俐.水热碳化技术处理畜禽粪便的研究进展[J].农业工程学报,2022,38(3):220-229. DOI:10.11975/j. issn.1002-6819.2022.03.026

Li Zifu, Yu Lu, Zheng Lei, Guo Jiali. Research progress of treatment of livestock manure by hydrothermal carbonization technology[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE),2022,38(3):220-229. DOI:10.11975/j. issn.1002-6819.2022.03.026

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2021-11-19
  • 最后修改日期:2022-01-06
  • 录用日期:
  • 在线发布日期: 2022-03-11
  • 出版日期:
文章二维码
您是第位访问者
ICP:京ICP备06025802号-3
农业工程学报 ® 2024 版权所有
技术支持:北京勤云科技发展有限公司